Brown the chicken (optional but recommended): Heat the oil in a skillet over medium-high. Sear the chicken in batches for 1–2 minutes per side until lightly golden.
You’re not cooking it through—just adding flavor. Transfer to the slow cooker.
Make the sauce: In a bowl, whisk together orange juice, orange zest, soy sauce, honey, rice vinegar, garlic, ginger, red pepper flakes, black pepper, and salt. Taste and adjust sweetness or acidity as needed.
Slow cook: Pour the sauce over the chicken.
Cover and cook on Low for 3–4 hours or on High for 1.5–2.5 hours, until the chicken is tender and reaches 165°F internally.
Thicken the sauce: Whisk cornstarch and cold water until smooth. Stir the slurry into the slow cooker. Cover and cook on High for 10–15 minutes, or until the sauce thickens and turns glossy.
Finish and serve: Taste and adjust seasoning.
Garnish with green onions and sesame seeds. Serve over rice with steamed veggies.